Event № 649
Advisor: Prof. Udi Yariv
Abstract: Surrounded by a spherically symmetric solute cloud, chemically active homogeneous spheres do not undergo conventional autophoresis when suspended in an unbounded liquid domain. When exposed to external flows, solute advection deforms that cloud, resulting in a generally asymmetric distribution of diffusio-osmotic slip which, in turn, modifies particle motion. We illustrate this phoretic phenomenon using two prototypic configurations, one where the particle sediments under a uniform force field and one where it is subject to a simple shear flow. In addition to the Peclet number associated with the imposed flow, the governing nonlinear problem also depends upon the intrinsic Peclet number associated with the chemical activity of the particle. As in the forced-convection problems, the small-Peclet-number limit is nonuniform, breaking down at large distances away from the particle. Calculation of the leading-order autophoretic effects thus requires use of matched asymptotic expansions. We considered two problems: sedimentation and shear problems. In the sedimentation problem we find an effective drag reduction; in the shear problem we find that the magnitude of the stresslet is decreased. For a dilute particle suspension the latter result is manifested by a reduction of the effective viscosity.